253MA

253MA (UNS S30815) is an austenitic heat-resistant stainless steel alloyed with silicon and cerium rare-earth elements. These additions produce a tightly adherent, multi-layer oxide scale that resists spallation under thermal cycling at temperatures up to 1100°C. The nitrogen content provides solid-solution strengthening, helping the alloy maintain creep resistance at service temperature.

1. Chemical Composition

The table below lists the elemental composition of 253MA. The rare-earth (cerium) and high-silicon additions are responsible for its oxidation resistance and strong scale adhesion.

GRADE UNS
Designation
C Mn P S Si Cr Ni Mo Ti Cu Al Other
253MAS308150.05-0.10.800.0400.0301.4-2.020.0-22.010.0-12.0N:0.14-0.20
Ce:0.03-0.08

Note: The cerium addition (0.03–0.08%) acts as an oxide scale modifier. It improves how well the chromia scale adheres to the steel surface during thermal cycling, a property that conventional austenitic heat-resistant grades lack.

2. Mechanical Properties

These are the minimum mechanical property values for 253MA in the solution-annealed condition. They reflect both ambient-temperature strength and suitability for structural use in high-temperature furnace environments.

Grade Condition & Size Standard Heat Treating Temp. : min Tensile Strength
Min. MPa
Yield Strength
Min. MPa
Elongation
min. %
253MAA3121040°C60031035

Note: At 900°C, 253MA keeps a 0.2% proof strength of roughly 70–80 MPa. This gives it useful load-bearing capacity at temperatures where standard 310 stainless steel softens considerably.

3. Equivalent Grade

This table shows international designation cross-references for 253MA. Equivalents are limited because its proprietary cerium-modified composition does not appear in most national standards.

GRADE UNS GB JIS ISO DIN/EN GOST
ISC NEW
253MA S30815 - 0Cr21Ni11N - X9CrNiSiNCe21-11 1.4835 -

Note: 253MA is a proprietary grade developed by Outokumpu (formerly Avesta Sheffield). EN 1.4893 is the recognized European equivalent. There are no direct equivalents in JIS, GB, or GOST.

3. Key Technical Advantages

  • Cerium-Modified Oxide Scale Adherence: The rare-earth cerium addition changes the oxide growth mechanism on the steel surface. Cerium segregates to oxide grain boundaries and the metal-oxide interface, where it suppresses oxide scale spallation during thermal cycling. This is the primary failure mechanism in conventional austenitic heat-resistant alloys above 900°C.
  • High Silicon for Oxidation Resistance Beyond Chromium Alone: Silicon at 1.4–2.0% forms a sub-layer of amorphous SiO2 beneath the primary chromia (Cr2O3) scale. This slows oxygen diffusion through the oxide layer and extends service life in air and combustion atmospheres up to 1100°C.
  • Nitrogen Solid-Solution Strengthening for Elevated-Temperature Creep: Nitrogen at 0.14–0.20% strengthens the austenitic matrix through solid solution, improving creep rupture life compared to equivalent chromium-nickel grades between 800°C and 1050°C. It does this without reducing ductility or formability.
  • Technical Note: 253MA is designed for cyclic oxidizing atmospheres, not reducing or sulfidizing environments. In sulfur-bearing combustion gases, the cerium and silicon additions do not protect against sulfide attack. High-nickel alloys are more appropriate for sulfidizing service. Welding should use matching 253MA filler or Sanicro 71 (ERNiCr-3) for full corrosion performance.

4. Common Manufacturing Standards

  • ASTM A312: Standard specification for seamless, welded, and heavily cold-worked austenitic stainless steel pipes. UNS S30815 is listed for heat-resistant service piping.
  • ASTM A213: Standard specification for seamless ferritic and austenitic alloy-steel boiler, superheater, and heat-exchanger tubes. S30815 is applicable for high-temperature service.
  • ASTM A249: Standard specification for welded austenitic steel boiler, superheater, heat-exchanger, and condenser tubes. The S30815 designation applies.
  • DIN EN 10216-5: Seamless steel tubes for pressure purposes, stainless steel (Grade 1.4893 equivalent).
  • GB/T 14976: Seamless stainless steel tubes for fluid transport. Material substitution review is required since no direct GB designation has been established.

Manufacturing Standards Comparison Table:

Standard ASTM EN/DIN JIS GB/T GOST
Seamless Pipe A312 S30815 EN 10216-5 (1.4893)
Seamless Tube A213 S30815 EN 10216-5 (1.4893)
Welded Tube A249 S30815 EN 10217-7 (1.4893)

5. Primary Applications

  • Radiant Tubes in Heat Treatment Furnaces: Electrically heated and gas-fired radiant tubes in batch and continuous heat treatment furnaces operating between 900–1100°C. In this range, 253MA's cyclic oxidation resistance extends tube service life well beyond standard 310 stainless steel.
  • Industrial Burner Components: Flame deflectors, burner baskets, and combustion chamber inserts in gas-fired industrial furnaces. These parts face frequent thermal cycling and high peak temperatures that spall conventional oxide scales.
  • Incinerator Afterburner Chambers: Structural components in waste incineration afterburner sections and thermal oxidizer vessels operating in aggressive mixed-atmosphere combustion gases at 900–1050°C.
  • Biomass and Waste-to-Energy Boilers: Superheater and reheater tube bundles in biomass-fired boilers. Alkali chloride deposits combined with high temperatures challenge both oxidation resistance and deposit-induced corrosion performance in these installations.
  • Ethylene Cracker Convection Section Tubes: Convection section tube coils in steam cracking furnaces where cyclic thermal loading and an oxidizing flue gas atmosphere make scale adhesion the primary material selection factor.
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